Product ID:DEMON WP INSECTICIDE
MSDS Date:09/24/1990
FSC:6840
NIIN:01-390-4822
Status Code:A
MSDS Number: CKXMV

ZENECA INC. ZENECA PHARMACEUTICALS GROUP (FORMERLY ICI

1800 CONCORD PIKE
WILMINGTON, DE 19897
US

Emergency Phone: (800)424-9300

Info Phone: 302-886-3000

Cage: 13992

ZENECA INC. ZENECA PHARMACEUTICALS GROUP (FORMERLY ICI

WILMINGTON, DE 19897 US

Telephone: 302-886-3000

Cage: 13992

CYPERMETHRIN CONCENTRATE 90%

CAS: 52315-07-8

RTECS: GZ1250000

OSHA PEL NOT LISTED

CALCIUM SILICATE

CAS: 1344-95-2

RTECS: VV9150000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

AMORPHOUS SILICA

CAS: 7631-86-9

OSHA PEL 6 MG/M3

OTHER INGREDIENTS

OSHA PEL NOT LISTED

LD50 LC50 Mixture:ORAL LD50(RAT): 1.8 G/KG
Health Hazards Acute and Chronic:INGESTION-RELATIVE TO OTHER MATERIALS,
A SINGLE DOSE OF PRODUCT IS SLIGHTLY TOXIC. EYE-IT WILL PROBABLY
IRRITATE HUMAN EYES. SKIN-IRRITATION WILL PROBABLY DEVELOP
FOLLOWING REPEATED/ PROLONGED CONTACT . DERMATITIS/SKIN
SENSITZATION CAN DEVELOP AFTER REPEATED/PROLONGED CONTACT WITH
HUMAN SKN. EXPOSURE MAY CAUSE PARESTHESIA, WHICH IS USUALLY
DESCRIBED AS TINGLING, ITCHING, BURNING, PRICKLING, GLOWING ,
FLUSHING, NUMBNESS OR A CHAPPED FEELING. SYMPTOMS OCCUR AROUND THE
FACE (MOUTH/EYES) BUT MAY INVOLVE THE ARMS/HANDS. SYMPTOMS DEVELOP
SHORTLY AFTER EXPOSURE OR BETWEEN 2-30 HRS. THERE IS NO EVIDENCE
OF LONG-TERM/CUMULATIVE EFFECTS.
Effects of Overexposure:NAUSEA,VOMITING WITH COLICKY PAIN, TENESMUS,
DIARRHEA, CONVULSIONS, UNCONSCIOUSNESS AND RESPIRATORY FAILURE CAN
DEVELOP FOLLOWING INGESTION OF THIS PRODUCT.

First Aid:SKIN-WASH MATERIAL OFF SKIN WITH PLENTY OF SOAP & WATER. IF
REDNESS, ITCHING OR A BURNING SENSATION DEVELOPS, GET MEDICAL AID.
WASH CONTAMINATED CLOTHING & DECONTAMINATE FOOTWEAR BEFORE REUSE.
EYES-IM MEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. IF
REDNESS, ITCHING OR A BURNING SENSATION DEVELOPS, HAVE EYES
EXAMINED & TREATED BY MEDICAL PERSONNEL. INGESTION-GIVE 1 OR 2
GLASSES OF WATER TO D RINK. IF GASTROINTESTINAL SYMPTOMS DEVELOP,
CONSULT MEDICAL PERSONNEL. (NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON) INHALATION: REMOVE PERSON TO FRESH AIR. IF
COUGH OR OTHER RESPIRATORY SYM PTOMS DEVELOP, SEE DOCTOR.

Autoignition Temp:Autoignition Temp Text:NO DAT
Lower Limits:NOT APPLICAB
Upper Limits:NOT APPLICAB
Extinguishing Media:WATER FOG, FOAM, CARBON DIOXCIDE, DRY CHEMICAL,
HALOGENATED AGENTS.
Fire Fighting Procedures:SPECIAL FIRE FIGHTING PROTECTIVE EQUIPMENT:
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE KNOWN

Spill Release Procedures:STEP TO BE TAKEN IN CASE MATERIAL IS RELEASED
OR SPILLED: WEAR SKIN, EYE AND RESPIRATORY PROTECTION DURING
CLEANUP. KEEP OUT OF SEWERS AND DRAINS. SWEEP UP AND RECOVER OR MIX
MATERIAL WITH MOIST ABSOR BENT AND SHOVEL INTO WASTE CONTAINER.

Handling and Storage Precautions:PRECAUTIONS TO BE TAKEN IN HANDLING OR
STORAGE. PREVENT SKIN AND EYE CONTACT. OBSERVE TLV LIMITATIONS. A
SENSITIZED INDIVIDUAL SHOULD NOT BE EXPOSED TO THIS PRODUCT WHICH
CAUSED THE SENSITZATION. DO NOT STORE NEAR FEED OR FOOD.
Other Precautions:CONTAINER DISPOSAL-EMPTY CONTAINER RETAIN PRODUCT
RESIDUE. OBSERVE ALL HAZARD PRECAUTION. DO NOT DISTRIBUTE, MAKE
AVAILABLE, FURNISH OR REUSE EMPTY CONTAINER EXCEPT FOR
STORAGE/SHIPMENT OF ORIGINAL ST OCK. REMOVE HAZARDOUS RESIDUE
USING APPROPIATE SOLVENTS. THEN OFFER FOR
RECYCLING/RECONDITIONING/PR ICK/DESTROY/DISPOSE.

Respiratory Protection:IF NEEDED, USE MSHA/NIOSH APPROVED RESPIRATOR
FOR PESTICIDES.
Ventilation:USE LOCAL EXHAUST TO KEEP EXPOSURE TO A MINIMUM.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL TIGHT GOGGLES.
Other Protective Equipment:EYEWASH STATION AND SAFETY SHOWER IN WORK
AREA. IMPERVIOUS GLOVES. DEPENDING ON CONDITIONS OF USE, ADDITIONAL
PROTECTION MAY BE REQUIRES SUCH AS APRON, ARM COVERS, ARM COVERS,
OR FULL BODY SUIT.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING AND DECOTAMINATE
FOOTWARE BEFORE REUSE.
Supplemental Safety and Health
HAZARD SUMMARY: PHYSICAL HAZARDS: NONE. HEALTH HAZARDS: INHALATION
(TLV), IRRITANT (SKIN, EYE), SKIN SENSITIZER, HARMFUL
(RESPIRATORY). READ THE ENTIRE MSDS FOR A MORE THOROUGH EVALUATION
OF THE HAZAR DS.

HCC:T4
Vapor Pres:NO DATA
Vapor Density:NO DATA
Spec Gravity:NO DATA
pH:8.6
Solubility in Water:DISPERSIBLE
Appearance and Odor:OFF WHITE. SLIGHTLY AROMATIC POWDER.

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS.
Hazardous Decomposition Products:COMBUSTION PRODUCTS: CARBON DIOXIDE,
CARBON MONOXIDE, NITROGEN OXIDES, AMMONIA, HALOGEN ACIDS, POSSIBLE
TRACE AMOUNTS OF CARBONYL HALLIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:THIS MATERIAL IS EXTREMELY TOXIC TO FISH. DO NOT
CONTAMINATE WATERWAYS BY CLEANING OF EQUIPMENT OR BY DISPOSAL OR
WASTE. UNTREATED EFFLUENT SHOULD NOTBE DISCHARGED WHERE IT WILL
DRAIN INTO LAKES, STRE AMS OR PONDS.

Toxicological Information:INGESTION: THE ACUTE ORAL LD50 IN RAT IS 1.8
G/KG. RELATIVE TO OTHER MATERIALS, A SINGLE DOSE OF THIS PRODUCT IS
SLIGHTLY TOXIC BY INGESTION. EYE CONTACT: THIS MATERIAL IS
MODERATELY IRRITATING IN A RABBIT EYE IRRITATION TEST. SKIN
CONTACT: THIS MATERIAL IS MILDLY IRRITATING IN A RABBIT DERMAL
IRRITATION TEST. THIS MATERIAL IS A SKIN SENSITIZER IN ANIMAL
TESTING. SKIN ABSORPTION: THE ACUTE DER MAL LD50 IN RABBITS IS
ABOVE 2.0 G/KG. SYSTEMICALLY TOXIC CONCENTRATIONS ARE UNLIKELY TO
BE ABSORBED THROUGH THE SKIB IN MAN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:CERCLA AND SARA REGULATIONS (40 CFR 355,
370, AND 372): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS SUBJECT
TO THE REPORTING REQUIREMENTS OF SARA SECTION 313.
Federal Regulatory Information:TSCA (TOXIC SUBSTANCE CONTROL ACT)
REGULATIONS, 40 CFR 710: THIS PRODUCT IS A PESTICIDE AND IS EXEMPT
FROM TSCA RGULATIONS.